Volume 13
Main Index

Issue 01

Masthead DOI: 10.1021/ar50145a700

Stereoregular and sequence-regular polymerization of butadiene Junji Furukawa pp 1–6 DOI: 10.1021/ar50145a001

Surfactant vesicles as membrane mimetic agents: characterization and utilization Janos H. Fendler pp 7–13 DOI: 10.1021/ar50145a002

Electron impact spectroscopy Sandor Trajmar pp 14–20 DOI: 10.1021/ar50145a003

Molecular multiphoton ionization spectroscopy Philip M. Johnson pp 20–26 DOI: 10.1021/ar50145a004

Oxycyclopropanes in organochemical synthesis Ernest Wenkert pp 27–31 DOI: 10.1021/ar50145a005

Issue 02

Masthead DOI: 10.1021/ar50146a700

Tandem mass spectrometry (MS/MS): a promising new analytical technique for specific component determination in complex mixtures Fred W. McLafferty pp 33–39 DOI: 10.1021/ar50146a001

Intramolecular iminium ion-sulfide charge-transfer association: a recurring theme in the study of thiaspirane alkaloids Robert T. LaLonde pp 39–44 DOI: 10.1021/ar50146a002

Exciplex intermediates in [2 + 2] photocycloadditions Richard A. Caldwell, David Creed pp 45–50 DOI: 10.1021/ar50146a003

Radical ipso attack and ipso substitution in aromatic compounds Marcello Tiecco pp 51–57 DOI: 10.1021/ar50146a004

Carbenic selectivity in cyclopropanation reactions Robert A. Moss pp 58–64 DOI: 10.1021/ar50146a005

Issue 03

Masthead DOI: 10.1021/ar50147a700

[2n]Cyclophanes: paracyclophane to superphane Virgil Boekelheide pp 65–70 DOI: 10.1021/ar50147a001

Benzocyclobutene and related compounds Randolph P. Thummel pp 70–76 DOI: 10.1021/ar50147a002

Bimolecular reactions of nucleophiles in the gas phase John H. Bowie pp 76–82 DOI: 10.1021/ar50147a003

Photoinduced electron transfer reactions of metal complexes in solution David G. Whitten pp 83–90 DOI: 10.1021/ar50147a004

Raman optical activity: a new probe of stereochemistry and magnetic structure Laurence D. Barron pp 90–96 DOI: 10.1021/ar50147a005

Issue 04

Masthead DOI: 10.1021/ar50148a700

Biosynthesis of tetrahymanol by Tetrahymena pyriformis: mechanistic and evolutionary implications Eliahu Caspi pp 97–104 DOI: 10.1021/ar50148a001

Crystal packing, hydrogen bonding, and the effect of crystal forces on molecular conformation Pnina Dauber, Arnold T. Hagler pp 105–112 DOI: 10.1021/ar50148a002

Use of isotope crossover experiments in investigating carbon-carbon bond-forming reactions of binuclear dialkylcobalt complexes Robert G. Bergman pp 113–120 DOI: 10.1021/ar50148a003

Mechanisms of carbon monoxide reduction with zirconium hydrides Peter T. Wolczanski, John E. Bercaw pp 121–127 DOI: 10.1021/ar50148a004

Issue 05

Masthead DOI: 10.1021/ar50149a700

Thermal lensing: a new spectroscopic tool David S. Kliger pp 129–134 DOI: 10.1021/ar50149a001

Chemically modified electrodes Royce W. Murray pp 135–141 DOI: 10.1021/ar50149a002

Energy surfaces of sigmatropic shifts Joseph J. Gajewski pp 142–148 DOI: 10.1021/ar50149a003

Flavin coenzymes: at the crossroads of biological redox chemistry Christopher Walsh pp 148–155 DOI: 10.1021/ar50149a004

Deciphering the protein-DNA recognition code Marvin H. Caruthers pp 155–160 DOI: 10.1021/ar50149a005

Issue 06

Masthead DOI: 10.1021/ar50150a700

When is an intermediate not an intermediate? Enforced mechanisms of general acid-base, catalyzed, carbocation, carbanion, and ligand exchange reaction William P. Jencks pp 161–169 DOI: 10.1021/ar50150a001

Biomimetic control of chemical selectivity Ronald Breslow pp 170–177 DOI: 10.1021/ar50150a002

Electrochemistry of well-defined surfaces Arthur T. Hubbard pp 177–184 DOI: 10.1021/ar50150a003

Calcium-induced conformational changes in the troponin-tropomyosin complexes of skeletal and cardiac muscle and their roles in the regulation of contraction-relaxation William D. McCubbin, Cyril M. Kay pp 185–192 DOI: 10.1021/ar50150a004

Issue 07

Masthead DOI: 10.1021/ar50151a700

Electron paramagnetic resonance and the art of physical-organic chemistry David Griller, Keith U. Ingold pp 193–200 DOI: 10.1021/ar50151a001

Chemistry of aliphatic thioether cation radicals and dications W. Kenneth Musker pp 200–206 DOI: 10.1021/ar50151a002

.alpha.-Acylcarbenium ions Jean Pierre Begue, Micheline Charpentier-Morize pp 207–212 DOI: 10.1021/ar50151a003

Trans-cycloalkenes and [a.b]betweenanenes, molecular jump ropes and double bond sandwiches James A. Marshall pp 213–218 DOI: 10.1021/ar50151a004

Allylic and propargylic imidic esters in organic synthesis Larry E. Overman pp 218–224 DOI: 10.1021/ar50151a005

Generation and transfer of triplet energy in enzymic systems Giuseppe Cilento pp 225–230 DOI: 10.1021/ar50151a006

Field-dependent magnetic phenomena Richard L. Carlin, A. J. Van Duyneveldt pp 231–236 DOI: 10.1021/ar50151a007

High-spin molecules Richard J. Van Zee, Charles M. Brown, Kyle J. Zeringue, William Weltner Jr. pp 237–242 DOI: 10.1021/ar50151a008

Alkylaminobis(difluorophosphines): novel bidentate ligands for stabilizing low metal oxidation states and metal-metal bonded systems R. Bruce King pp 243–248 DOI: 10.1021/ar50151a009

Issue 08

Masthead DOI: 10.1021/ar50152a700

A role for manganese in oxygen evolution in photosynthesis Kenneth Sauer pp 249–256 DOI: 10.1021/ar50152a001

Mechanisms of flavin catalysis Thomas C. Bruice pp 256–262 DOI: 10.1021/ar50152a002

Elucidation and formulation of novel biosynthetic pathways leading to the pyrrolo[1,4]benzodiazepine antibiotics anthramycin, tomaymycin, and sibiromycin Laurence H. Hurley pp 263–269 DOI: 10.1021/ar50152a003

o-Xylylenes and isoindenes as reaction intermediates John J. McCullough pp 270–276 DOI: 10.1021/ar50152a004

Structural criteria for the mode of bonding of organoactinides and -lanthanides and related compounds Kenneth N. Raymond, Charles W. Eigenbrot Jr. pp 276–283 DOI: 10.1021/ar50152a005

Crystal lattice control of unimolecular photorearrangements John R. Scheffer pp 283–290 DOI: 10.1021/ar50152a006

A van der Waals picture of the isotropic-nematic liquid crystal phase transition William M. Gelbart, Boris Barboy pp 290–296 DOI: 10.1021/ar50152a007

Issue 09

Masthead DOI: 10.1021/ar50153a700

Synthesis and transport of juvenile hormones in insects Steven J. Kramer, John H. Law pp 297–303 DOI: 10.1021/ar50153a001

"Ordered" distribution of electrically charged solutes in dilute solutions Norio Ise, Tsuneo Okubo pp 303–309 DOI: 10.1021/ar50153a002

Structure of a green bacteriochlorophyll protein Brian W. Matthews, Roger E. Fenna pp 309–317 DOI: 10.1021/ar50153a003

Free-radical clocks David Griller, Keith U. Ingold pp 317–323 DOI: 10.1021/ar50153a004

Catalysis of chemical reactions by electrodes Jean Michel Saveant pp 323–329 DOI: 10.1021/ar50153a005

Some new synthetic reagents and reactions George A. Olah pp 330–336 DOI: 10.1021/ar50153a006

Issue 10

Masthead DOI: 10.1021/ar50154a700

Purple membrane of halobacteria: a new light-energy converter Walther Stoeckenius pp 337–344 DOI: 10.1021/ar50154a001

Citrate conformation and chelation: enzymic implications Jenny P. Glusker pp 345–352 DOI: 10.1021/ar50154a002

Spin-pairing model of dioxygen binding and its application to various transition-metal systems as well as hemoglobin cooperativity Russell S. Drago, Barry B. Corden pp 353–360 DOI: 10.1021/ar50154a003

Optical molecular dephasing: principles of and probings by coherent laser spectroscopy Ahmed H. Zewail pp 360–368 DOI: 10.1021/ar50154a004

Magnetic field and magnetic isotope effects in organic photochemical reactions. A novel probe of reaction mechanisms and a method for enrichment of magnetic isotopes Nicholas J. Turro, Bernhard Kraeutler pp 369–377 DOI: 10.1021/ar50154a005

Chemical reactions and the nature of comets Michael Oppenheimer pp 378–384 DOI: 10.1021/ar50154a006

Issue 11

Masthead DOI: 10.1021/ar50155a700

New rules of selectivity: allylic alkylations catalyzed by palladium Barry M. Trost pp 385–393 DOI: 10.1021/ar50155a001

A perspective of ribulose bisphosphate carboxylase/oxygenase, the key catalyst in photosynthesis and photorespiration Bruce A. McFadden pp 394–399 DOI: 10.1021/ar50155a002

The J method: application of NMR spectroscopy to the determination of small internal rotation barriers in solution William J. E. Parr, Ted Schaefer pp 400–406 DOI: 10.1021/ar50155a003

Surface structure determinations with ion beams Nicholas Winograd, Barbara J. Garrison pp 406–412 DOI: 10.1021/ar50155a004

Chemical applications of extended x-ray absorption fine structure (EXAFS) spectroscopy Boon-Keng Teo pp 412–419 DOI: 10.1021/ar50155a005

Mechanism of the ene reaction between singlet oxygen and olefins L. M. Stephenson, Mary Jo Grdina, Michael Orfanopoulos pp 419–425 DOI: 10.1021/ar50155a006

Lewis-acid catalyzed ene reactions Barry B. Snider pp 426–432 DOI: 10.1021/ar50155a007

Issue 12

Masthead DOI: 10.1021/ar50156a700

Influence of molecular structure on stopping power of chemical species for helium(+) ions from a low-energy particle accelerator Darden Powers pp 433–440 DOI: 10.1021/ar50156a001

Variational transition-state theory Donald G. Truhlar, Bruce C. Garrett pp 440–448 DOI: 10.1021/ar50156a002

Stereospecific reactions of nitrilium ions and analogous 1,3-dipoles Anthony Hegarty pp 448–454 DOI: 10.1021/ar50156a003

Stereochemistry of pyridoxal phosphate catalyzed enzyme reactions John C. Vederas, Heinz G. Floss pp 455–463 DOI: 10.1021/ar50156a004

Tricarbonyl(diene)iron complexes: synthetically useful properties Anthony J. Pearson pp 463–469 DOI: 10.1021/ar50156a005

Synthesis, molecular dynamics, and reactivity of mixed-metal clusters Gregory L. Geoffroy pp 469–476 DOI: 10.1021/ar50156a006